Two ways to add rake. One is to change the actual steering stem angle. That generally means cutting and welding the frame. For some bikes, (notably Harleys,) you can get bearing sets with offset outer races that change the angle 3 degrees without frame modification.
The other way is raked triple trees.
These two methods have totally opposite effects on steering geometry. Raking the frame adds trail to the geometry. This can lead to heavy, cumbersome handling. The bike becomes less nimble. It wants to go in straight lines and requires extra input from the rider to make it turn. It can also cause a low speed, "flopover" effect, where by pure gravitty effects, the front end wants to go to full lock one way or the other just from the weight of the bike. As the bike moves faster, this effect goes away.
Raking the trees reduces trail. This makes the bike highly maneuverable and nimble. It corners easily, but may lack straight line stability, even to the point of inducing "tank slappers."
Ideally, if you want to increase rake, do some of it with the frame, and some with the trees. This gives you a balanced approach to get the stance that you want without excessive negative impact on handling characteristics.
Here is a rake and trail calculator. Play around with it and you will get a feel for what you can do to keep your bike within an acceptable range of characteristics.
http://207.57.8.251/tools/rake_trail.html