So maybe make a few bends with a template so you can control the radius, and then cut them to the degrees of turn you need (you'll need that info for the cnc bender) and connect with the straight bits (also needed for the cnc). You'll also need the degrees of axial rotation from one turn to the next. All of these things will be hard to make and measure accurately compared to the cnc bender so your process will be important. If you have a care to make good square cuts, you can simply glue them together end to end. Adjustments would be easy, as you can simply cut them back apart, make whatever changes you need and glue them back together. At the end you should have a good fit with an accurate record to give to the bender. You will have to be super careful to be accurate - even a really tiny miss-measurement will throw off the result considerably when made by the bender. The good news is that after the first pipe is bent, it will be pretty easy (though not cheap!) to tweak the program to hone in on perfection. The bender I have seen reproduced unbelievably identical parts so tiny adjustment were very reliable. I think you will find bending the pvc around a form like a can doesn't work like you think it will. Just get a heat gun and make a few tests and you will see you get a fairly floppy rubbery result that you can simply hold in place while it cools and keeps its new shape. I have made very accurate bends simply by laying the heated pipe on top of some layout lines drawn on some plywood. I would definitely try Mr. irk's sand technique to help keep the diameter under control. I obviously have not tried it but I bet it works great.