Didn't have carbs on?
How fast are you turning motor?
Need about 10 sec with electric start or 5~10 good kicks so motor is spinning
If valve adjustment is correct you'll have a lot more than 95psi, unless valve is actually bent
Did you try putting head on edge (intake ports standing on bench) and fill exhaust ports with kerosene, diesel, etc?
bent or leaking valves are real obvious.
After you check exhaust valves, tip fluid into a bucket or something, flip head onto exhaust ports and fill up intakes
If combustion chambers remain dry, valves are not a problem